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At what point does heat become a problem when storing your pheromones?

I keep my pheromones inside cigar boxes to keep the light out and I have a couple in my backpack at all times. I am pretty anal about trying to keep them cool but my main stash at home is upstairs and it gets above 80f at times.

Does heat effect the actual molecular composition or is it mainly evaporation that is the prime concern?

Should I store them somewhere else in the house? At what temp
Do you start to have major problems. Like can they get 100f and still be ok?

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